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Problem: Optimum transmission of a medium for the determination of concentration of scattering/absorbing centers

The relative error, dc/c, of the determination of the attenuation coefficient, c, assumes a minimum for a pathlength, z, in a medium which equals 1/c, according to the following equation:

 dc / c = - 1/ [ cz exp(-cz) ] / Φ0  (1)

(see Measuring attenuation of light: Optimum pathlength). By using the Beer-lambert law, prove that the above equation leads to the following formula for the relative error of the concentration, n, of the scattering and/or absorbing centers in the medium:

 dn / n = (1 / lnT ) (dT / T )  (2)

where T is the transmission of the medium at a pathlength z. Assume that the photon shot noise is negligible.

CITATION:
Swanson N. L., Jonasz M. 2007. Problem: Optimum transmission of a medium for the determination of concentration of scattering/absorbing centers (www.tpdsci.com/Tpc/AtnCfMsOptmT_P.php). In: Top. Part. Disp. Sci. (www.tpdsci.com).
HISTORY:
Published: 25-Oct-2007
Modified: 25-Oct-2007
Peer-reviewed: PENDING
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