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Scattering coefficient of seawater vs. temperature and salinity

Scattering by seawater as a function of temperature and salinity


Fig. 1. The scattering coefficient of pure seawater at 546 nm as a function of temperature and salinity as evaluated by using the following equations based on a thermodynamic model of light scattering:

b = bd + bc  
  = 8 π3 / λ4 [ρn/∂ρ]T2 kT βT h (δ) +  
     8 π3 / ( λ4 NA ) [ ∂n/∂S ]2 ( MW / ρ ) S (-∂lnaw / ∂S )-1 h (δ) (1)

where λ is the wavelength of light in vacuum, ρ is the specific density of water, n is the refractive index of water, T is the absolute temperature, k is the Boltzmann constant, βT is the isothermal compressibility of water, δ is the depolarization ratio, MW is the molecular weight of water, S is the salinity, aw is the activity of water, and

h(δ) = (2 + δ ) / ( 6 - 7 δ) (2)

Term bd  represents a contribution of density fluctuations to the scattering coefficient, while bc represents a contribution of the salts concentration fluctuations. The values of the parameters of the above equations and expressions for their calculations are listed by Zhang X et al 2009 and Zhang X and Hu 2009 (see also a data file and a Matlab code). The broken line connects the salinity-dependent positions of minima of the scattering coefficient.   Redrawn by permission from Zhang X and Hu 2010. [XZ]

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